Fix some issues with experimental config settings

Issues:

1. Features gated on disabled experimental settings should warn and be
   ignored, not silently succeed.

2. Experimental settings in the same config "batch" (file or env var)
   as the enabling of the experimental feature should work.

3. For (2), the order should not matter.

These are analogous to the issues @roberth caught with my changes for
arg handling, but they are instead for config handling.

Co-authored-by: Robert Hensing <roberth@users.noreply.github.com>

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